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AN4348 Datasheet(PDF) 5 Page - STMicroelectronics

Part # AN4348
Description  Signal conditioning for electrochemical sensors
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Manufacturer  STMICROELECTRONICS [STMicroelectronics]
Direct Link  http://www.st.com
Logo STMICROELECTRONICS - STMicroelectronics

AN4348 Datasheet(HTML) 5 Page - STMicroelectronics

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AN4348
Signal conditioning with a three-electrode sensor
DocID025166 Rev 1
5/25
2
Signal conditioning with a three-electrode sensor
To use a three-electrode sensor, a voltage has to be applied between the WE and the RE
according to the specification of the sensor. The current generated on the WE has to be
balanced by the electronics on the CE. No current should flow through the RE. A trans-
impedance amplifier configuration is used to convert the current generated by the sensor
into a voltage that can be read by the ADC of a microcontroller. This whole electronic
design is called a potentiostat. Sensors are generally specified for a given resistive load
which must be "seen"
by the sensor. This value is generally in the range 10 Ω to 100 Ω.
Figure 4 exhibits the main parts of the potentiostat circuitry. The U1 op-amp converts the
current generated by the sensor into a voltage thanks to RT. The output voltage sensed by
the ADC is then RT×Isense. Note that depending on the sensor (gas detected) this current
can be either positive or negative (see Figure 2 and Figure 3). U1 also ensures that the
sensor is loaded by the specified load (RL) and keeps the working electrode at a fixed
potential. U2 fixes the specified voltage between the WE and the RE (VWE-VRE = -Vref). It
also ensures that no current flows through the RE while providing the right amount of
current to the CE to compensate the one on the WE.
The microcontroller then computes the gas concentration from the reading made by its
ADC as the gas concentration is proportional to Isense.
Figure 4: Potentiostat principle


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